Unit A: Energy & Matter in Chemical Change
Ms. Terkper's Digital Classroom
Focusing Questions
"How has knowledge of the structure of matter led to other scientific advancements? How do elements combine? Can these combinations be classified and the products be predicted and quantified? Why do scientists classify chemical change, follow guidelines for nomenclature, and represent chemical change with equations?"
Program Outcomes
Key Concepts
Atomic Theory
| Scientist | Year | Model | Evidence |
|---|---|---|---|
| Dalton | 1803 | Solid sphere ("billiard ball") | Law of definite proportions; Law of multiple proportions |
| Thomson | 1897 | "Plum pudding" — electrons embedded in positive mass | Discovery of electron via cathode ray tube |
| Rutherford | 1911 | Nuclear model — dense positive nucleus, electrons orbit far away | Gold foil experiment (alpha particle scattering) |
| Bohr | 1913 | Planetary model — electrons in fixed energy levels/shells | Hydrogen emission spectrum |
| Modern (Quantum) | 1926+ | Electron cloud/orbital model | Wave mechanics, Schrodinger equation |
| Particle | Symbol | Charge | Location | Rel. Mass |
|---|---|---|---|---|
| Proton | p+ | +1 | Nucleus | 1 |
| Neutron | n0 | 0 | Nucleus | 1 |
| Electron | e- | -1 | Electron shells | 1/1836 |
Atomic Number, Mass Number, Isotopes
- Carbon-12: 6 protons, 6 neutrons (Mass = 12)
- Carbon-14: 6 protons, 8 neutrons (Mass = 14)
Bohr Diagram Rules
- Nucleus contains protons and neutrons in the center.
- Electrons are placed in energy levels (shells) around the nucleus.
- Shell 1: Maximum 2 electrons
- Shell 2: Maximum 8 electrons
- Shell 3: Maximum 8 electrons
- Always fill the lowest energy level first before moving to the next.
Periodic Table & Compounds
Periodic Table Groups and Trends
| Group / Category | Characteristics & Valence Electrons | Typical Ion Charge |
|---|---|---|
| Group 1: Alkali Metals | Highly reactive metals. 1 valence electron. | +1 |
| Group 2: Alkaline Earth Metals | Reactive metals. 2 valence electrons. | +2 |
| Groups 3–12: Transition Metals | Complex electron arrangements, multivalent (can form multiple ions). | Variable (e.g., +2, +3) |
| Group 17: Halogens | Highly reactive non-metals. 7 valence electrons. | −1 |
| Group 18: Noble Gases | Unreactive, stable non-metals. Full valence shell (8 electrons). | 0 |
Periods (rows): Indicate the number of occupied electron shells. Elements in period 3 have electrons in 3 shells.
Ion Formation
Metals lose electrons to form positive ions (cations).
Non-metals gain electrons to form negative ions (anions).
Fe2+, Fe3+, Cu+, Cu2+
NH4+ (Ammonium)
OH−, NO3−
SO42−, CO32−, PO43−
Formula Writing
To write the formula for an ionic compound, balance the total positive and negative charges to zero.
2. Aluminum oxide: Al3+ O2− → Al2O3
3. Iron(III) sulfate: Fe3+ SO42− → Fe2(SO4)3
4. Magnesium nitride: Mg2+ N3− → Mg3N2
5. Sodium carbonate: Na+ CO32− → Na2CO3
IUPAC Naming Rules
Name = metal name + non-metal name (change ending to -ide).
If the metal has a variable charge, use Roman numerals in parentheses.
FeCl2 = iron(II) chloride
FeCl3 = iron(III) chloride
CaCO3 = calcium carbonate
Al2(SO4)3 = aluminum sulfate
Use Greek prefixes: mono, di, tri, tetra, penta, hexa, hepta, octa, nona, deca.
First element gets a prefix ONLY if more than one. Second element always gets a prefix and ends in -ide.
CO2 = carbon dioxide
N2O4 = dinitrogen tetroxide
PCl5 = phosphorus pentachloride
Binary (no oxygen): hydro- + root + -ic acid.
Oxyacids (with oxygen): polyatomic ion name determines ending (−ate → −ic, −ite → −ous).
H2S = hydrosulfuric acid
H2SO4 = sulfuric acid
HNO3 = nitric acid
H3PO4 = phosphoric acid
CH3COOH = ethanoic (acetic) acid
Properties Comparison
| Property | Ionic | Molecular |
|---|---|---|
| Elements | Metal + Non-metal | Non-metals only |
| Bonding Type | Transfer of electrons | Sharing of electrons |
| State at RT | Solid crystal lattice | Solid, liquid, or gas |
| Melting Point | High | Relatively low |
| Conductivity | Conducts in solution/liquid | Does not conduct |
| Solubility | High solubility in water | Variable solubility |
| Examples | NaCl, CaCO3 | H2O, CO2, C6H12O6 |
Solubility Quick Rules
- • All Group 1 and NH4+ compounds are soluble.
- • All nitrates (NO3−) are always soluble.
- • Most chlorides are soluble (except AgCl, PbCl2).
- • Most sulfates are soluble (except BaSO4, PbSO4).
- • Most carbonates are generally insoluble (except Group 1/NH4+).
WHMIS 2015 Safety Symbols
Chemical Reactions & Equations
| Exothermic | Endothermic | |
|---|---|---|
| Energy flow | Released to surroundings | Absorbed from surroundings |
| Temperature change | Surroundings get warmer | Surroundings get cooler |
| Examples | Combustion, cellular respiration, neutralization, hand warmers | Photosynthesis, cold packs, baking soda + citric acid |
5 Types of Chemical Reactions
1. Synthesis (Formation)
• N2 + 3H2 → 2NH3
• 2Na + Cl2 → 2NaCl
2. Decomposition
• 2H2O2 → 2H2O + O2
• CaCO3 → CaO + CO2
3. Single Replacement
Metal replaces metal, or nonmetal replaces nonmetal.
• 2Na + 2H2O → 2NaOH + H2
• Mg + CuSO4 → MgSO4 + Cu
4. Double Replacement
• BaCl2 + Na2SO4 → BaSO4 + 2NaCl
• HCl + NaOH → NaCl + H2O
5. Hydrocarbon Combustion
• Complete: C3H8 + 5O2 → 3CO2 + 4H2O
Incomplete combustion (less O2) produces CO or C (soot) instead of CO2.
Balancing Chemical Equations
Step-by-Step Guide
- Rules: Coefficients go in front; subscripts CANNOT change; same number of atoms on both sides; conservation of mass.
- Step 1: Write the unbalanced equation.
- Step 2: Count atoms of each element on both sides.
- Step 3: Add coefficients to balance. Tip: Balance metals first, then non-metals, then hydrogen, then oxygen last.
- Step 4: Recount to verify.
Worked Examples
Answer: 2H2 + O2 → 2H2O
Answer: CH4 + 2O2 → CO2 + 2H2O
Answer: 4Fe + 3O2 → 2Fe2O3
Answer: 2Al + 6HCl → 2AlCl3 + 3H2
Answer: C3H8 + 5O2 → 3CO2 + 4H2O
Law of Conservation of Mass
Lavoisier's law states that matter cannot be created or destroyed in a chemical reaction. The total mass of reactants equals the total mass of products.
If 10g of H2 reacts completely with 80g of O2, what mass of water forms?
10g + 80g = 90g (Product)
The Mole Concept
What is a Mole?
1 mole = 6.02 × 1023 particles
This is Avogadro's number. It is the SI unit for amount of substance. Just like a "dozen" means 12 of something, a "mole" means 6.02 × 1023 of something.
Molar Mass (M)
The mass of 1 mole of a substance in grams. It equals the atomic mass from the periodic table, measured in g/mol.
The Calculation Triangle
= 120.24 + 2(94.97) = 310.18 g/mol
Moles and Balanced Equations
Introduction to stoichiometry. The coefficients in a balanced equation represent the mole ratio between reactants and products.
The "2:1:2" ratio means: 2 moles of H2 reacts exactly with 1 mole of O2 to produce 2 moles of H2O.
If you start with 4 moles of O2, how many moles of H2O can you make?
Answer: Since the ratio of O2 to H2O is 1:2, you multiply by 2. You can make 8 moles of H2O.
Interactive Practice & Quizzes
Equation Balancer
Adjust the coefficients to satisfy the Law of Conservation of Mass.
Interactive Equation Balancer
IUPAC Naming
Test your knowledge of ionic, molecular, and acid nomenclature.
IUPAC Naming Practice
Reaction Types
Identify the five major types of chemical reactions.
Classify the Reaction
Mole Calculations
Practice converting between mass, moles, and number of particles.
Mole Calculation Practice
Problem 1 / 8Vocabulary Flashcards
Review key terms for the unit exam. Click a card to flip it.